Bis(2-methyl-1H-imidazole-κN3)bis[2-(naphthalen-2-yl)acetato-κO]copper(II)

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Bis­(2-methyl-1H-imidazole-κN 3)bis[2-(naphthalen-2-yl)acetato-κO]copper(II)

In the crystal structure of the title compound, [Cu(C(12)H(9)O(2))(2)(C(4)H(6)N(2))(2)], the Cu(II) cations are square-planar coordinated by two 1-naphthyl-acetate anions and two 2-methyl-imidazole ligands into discrete complexes that are located on centres of inversion. These complexes are linked into chains parallel to [010] by inter-molecular N-H⋯O hydrogen bonding between the N-H H atom of ...

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Diaqua­bis­(1-methyl-1H-imidazole-κN 3)bis­[2-(naphthalen-1-yl)acetato-κO]cobalt(II)

In the title compound, [Co(C(12)H(9)O(2))(2)(C(4)H(6)N(2))(2)(H(2)O)(2)], the Co(II) ion is located on an inversion centre and displays a distorted octa-hedral coordination geometry. Two O atoms from two water mol-ecules and two carboxyl-ate O atoms from two 2-(naphthalen-1-yl)acetate ligands are in the equatorial plane and two N atoms from two 1-methyl-1H-imidazole ligands are in the axial pos...

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1-[(2-Methyl-8-quinol­yl)amino­methyl­ene]naphthalen-2(1H)-one

The mol-ecule of the title compound, C(21)H(16)N(2)O, exists in the keto form and the C=O and N-H bonds are mutually cis in the crystal structure, although an enol form would be possible through tautomerism. The dihedral angle between the quinoline and the naphthalene systems is 22.04 (2)°. A bifurcated intramolecular N-H⋯(O,N) hydrogen bond is present.

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Bis(1-methyl-1H-imidazole-κN 3)bis­[2-(naphthalen-1-yl)acetato-κO]copper(II) monohydrate

In the crystal structure of the title compound, [Cu(C(12)H(9)O(2))(2)(C(4)H(6)N(2))(2)]·H(2)O, the Cu(II) atom is coordinated by two 2-(naphthalen-1-yl)acetate anions and two 1-methyl-imidazole ligands, giving monomeric complexes with a square-planar coordination environment. Two complex mol-ecules and two water mol-ecules form a centrosymmetric ring system via O-H⋯O hydrogen bonds.

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Dichloridotris(2-methyl-1H-imidazole-κN 3)cadmium

In the title compound, [CdCl(2)(C(4)H(6)N(2))(3)], the Cd(II) atom displays a penta-coordinate CdN(3)Cl(2) coordination geometry, being coordinated by an N atom of three 2-methyl-imidazole ligands and two Cl atoms. In the crystal, the mononuclear complexes are linked by N-H⋯Cl hydrogen bonds into a two-dimensional network in the ab plane.

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2011

ISSN: 1600-5368

DOI: 10.1107/s1600536811047969